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  • Title: Indium mediated allylation of glyoxylate oxime ethers, esters and cyanoformates.
    Author: Ritson DJ, Cox RJ, Berge J.
    Journal: Org Biomol Chem; 2004 Jul 07; 2(13):1921-33. PubMed ID: 15227546.
    Abstract:
    An indium mediated procedure has been developed for the allylation of activated O-functionalised oximes and nitriles as exemplified by a variety of glyoxylate derivatives. This method gives the corresponding free (or protected) amine in a one pot-process. The method is regiospecific and is carried out under remarkably mild conditions so that even oxime esters can be subjected to the typical reaction conditions.
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