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  • Title: Cu(I)-mediated reductive amination of boronic acids with nitroso aromatics.
    Author: Yu Y, Srogl J, Liebeskind LS.
    Journal: Org Lett; 2004 Jul 22; 6(15):2631-4. PubMed ID: 15255708.
    Abstract:
    [reaction: see text] A mild method for the reductive amination of aryl boronic acids with nitroso aromatic compounds is reported. This C-N bond formation is mediated by a stoichiometric amount of CuCl as both a catalyst and a reducing agent. Alternatively, 10% Cu(I)-3-methylsalicylate (CuMeSal) catalyzes the same reaction in the presence of either ascorbic acid or hydroquinone as the terminal reducing agent. Diarylamines bearing a variety of functional groups can be obtained in good yields.
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