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  • Title: Synthesis and co-polymerization of an unsaturated 1,5-anhydro-D-fructose derivative.
    Author: Deppe O, Glümer A, Yu S, Buchholz K.
    Journal: Carbohydr Res; 2004 Aug 23; 339(12):2077-82. PubMed ID: 15280052.
    Abstract:
    An unsaturated derivative, 3,6-di-O-acetyl-1,5-anhydro-4-deoxy-D-glycero-hex-3-enopyranos-2-ulose (3), was obtained via regioselective elimination and acetylation of monohydrated 1,5-anhydro-D-fructose (1) in a single step reaction. High yield (80%) was achieved without any dimeric by-products. Its co-polymerization to saccharide polymers was investigated with different commercial vinyl co-monomers. Co-polymers were obtained and characterized.
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