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  • Title: Total synthesis of (-)-reveromycin a.
    Author: El Sous M, Ganame D, Tregloan PA, Rizzacasa MA.
    Journal: Org Lett; 2004 Aug 19; 6(17):3001-4. PubMed ID: 15330668.
    Abstract:
    The asymmetric total synthesis of (-)-reveromycin A is described. The key steps involved a Lewis acid catalyzed inverse electron demand hetero-Diels-Alder reaction followed by hydroboration/oxidation to afford the spiroketal core 4 in a highly stereoselective manner and introduction of the C18 hemisuccinate by high-pressure acylation.
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