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Title: Construction of supramolecular polymers with alternating alpha-, beta-cyclodextrin units using conformational change induced by competitive guests. Author: Miyauchi M, Harada A. Journal: J Am Chem Soc; 2004 Sep 22; 126(37):11418-9. PubMed ID: 15366870. Abstract: Supramolecular polymers having alternating alpha- and beta-cyclodextrin (CD) units have been prepared by using conformational change induced by competitive guests. Although each CD unit does not form intermolecular complexes, a mixture of an alpha-CD derivative and a beta-CD derivative formed intermolecular complexes to give supramolecular polymers having alternating CD units. This is the first example of construction of supramolecular polymers with alternating alpha-, beta-cyclodextrin units.[Abstract] [Full Text] [Related] [New Search]