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  • Title: Enzymatic synthesis of a ring-contracted analogue of 5-enolpyruvylshikimate-3-phosphate.
    Author: An M, Bartlett PA.
    Journal: Org Lett; 2004 Oct 28; 6(22):4065-7. PubMed ID: 15496100.
    Abstract:
    [reaction: see text] Three ring-contracted mimics of shikimate-3-phosphate, formed from the triols by shikimate kinase, were evaluated as substrates of the next enzyme in the pathway, EPSP synthase. The cyclopentylidene analogue (+)-2P was converted enzymatically to the enolpyruvyl derivative, thus demonstrating the second step of an artificial biosynthetic sequence.
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