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  • Title: BINOL catalyzed enantioselective addition of titanium phenylacetylide to aromatic ketones.
    Author: Cozzi PG, Alesi S.
    Journal: Chem Commun (Camb); 2004 Nov 07; (21):2448-9. PubMed ID: 15514809.
    Abstract:
    An enantioselective addition of titanium phenylacetylide to ketones, promoted by BINOL, is described; this new enantioselective protocol gives high enantiomeric excess (up to 90% ee) with aromatic ketones using a simple procedure without pyrophoric or expensive reagents.
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