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  • Title: Chiral self-dimerization of vanadium complexes on a SiO2 surface: the first heterogeneous catalyst for asymmetric 2-naphthol coupling.
    Author: Tada M, Taniike T, Kantam LM, Iwasawa Y.
    Journal: Chem Commun (Camb); 2004 Nov 21; (22):2542-3. PubMed ID: 15543270.
    Abstract:
    The self-dimerized chiral assembly of vanadium-Schiff-base complexes was found to occur on a SiO2 surface and to be the first heterogeneous catalyst for the asymmetric oxidative coupling of 2-naphthol with 100% selectivity and 90% enantioselectivity.
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