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  • Title: Aqueous hydrogenation of carbon dioxide catalysed by water-soluble ruthenium aqua complexes under acidic conditions.
    Author: Hayashi H, Ogo S, Fukuzumi S.
    Journal: Chem Commun (Camb); 2004 Dec 07; (23):2714-5. PubMed ID: 15568081.
    Abstract:
    Hydrogenation of carbon dioxide (P(H2/CO2)= 5.5/2.5 MPa) into formic acid (HCOOH) under acidic conditions (pH 2.5-5.0) in water has been achieved by using water-soluble ruthenium aqua catalysts [(eta6-C6Me6)RuII(L)(OH2)]SO4 (L = 2,2'-bipyridine or 4,4'-dimethoxy-2,2' bipyridine).
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