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  • Title: Pyramidalization of Gd3N inside a C80 cage. The synthesis and structure of Gd3N@C80.
    Author: Stevenson S, Phillips JP, Reid JE, Olmstead MM, Rath SP, Balch AL.
    Journal: Chem Commun (Camb); 2004 Dec 21; (24):2814-5. PubMed ID: 15599420.
    Abstract:
    The X-ray crystal structure of Gd(3)N@C(80).Ni(II)(OEP).1.5(benzene) shows that the Gd(3)N unit within the I(h) C(80) cage is pyramidal, whereas Sc(3)N@C(80), Sc(3)N@C(78), Sc(3)N@C(68), Lu(3)N@C(80) and Sc(2)ErN@C(80) have planar M(3)N units.
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