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  • Title: Gamma-p-toluenesulfonyl-alpha,beta-epoxysilane: a new and practical acrolein beta-anion equivalent.
    Author: Sasaki M, Takeda K.
    Journal: Org Lett; 2004 Dec 23; 6(26):4849-51. PubMed ID: 15606082.
    Abstract:
    [reaction: see text] Reaction of gamma-p-toluenesulfonyl-alpha,beta-epoxysilane with alkyl halides and aldehydes followed by treatment with n-Bu4NF affords alpha,beta-unsaturated aldehydes via a Brook rearrangement-mediated tandem process under extremely mild conditions.
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