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  • Title: Metal carbonyl derivatives of sulfur-containing quinones and hydroquinones: synthesis, structures, and electrochemical properties.
    Author: Adams RD, Miao S.
    Journal: Inorg Chem; 2004 Dec 27; 43(26):8414-26. PubMed ID: 15606190.
    Abstract:
    The reaction of CpMoMn(mu-S(2))(CO)(5), 1, with 1,4-benzoquinone in the presence of irradiation with visible light yielded the quinonedithiolato complex CpMoMn(CO)(5)(mu-S(2)C(6)H(2)O(2)), 2. The new complex CpMoMn(CO)(5)(mu-S(2)C(6)Cl(2)O(2)) (4) was synthesized similarly from 1 and 2,3-dichloro-1,4-benzoquinone. Compounds 2 and 4 were reduced with hydrogen to yield the hydroquinone complexes CpMoMn(CO)(5)[mu-S(2)C(6)H(2)(OH)(2)], 3, and CpMoMn(CO)(5)[mu-S(2)C(6)Cl(2)(OH)(2)], 5. UV-vis irradiation of solutions of Fe(2)(CO)(6)(mu-S(2)) and 1,4-benzoquinone yielded the hydroquinone complex Fe(2)(CO)(6)[mu-S(2)C(6)H(2)(OH)(2)], 6. Compound 6 was oxidized to the quinone complex Fe(2)(CO)(6)(mu-S(2)C(6)H(2)O(2)), 7, by using 2,3-dichloro-5,6-dicyano-1,4-benzoquinone. Substitution of the CO ligands on 6 by PPh(3) yielded the derivatives Fe(2)(CO)(5)(PPh(3))[mu-S(2)C(6)H(2)(OH)(2)], 8, and Fe(2)(CO)(4)(PPh(3))(2)[mu-S(2)C(6)H(2)(OH)(2)], 9. The electrochemical properties of 3, 5, 6, 8, and 9 were measured by cyclic voltammetry. The molecular structure of each of the new compounds 2-9 was established by single-crystal X-ray diffraction analyses.
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