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  • Title: Synthesis, electrochemistry, absorption and electro-polymerization of aniline-ethynyl metalloporphyrins.
    Author: Lin CY, Hung YC, Liu CM, Lo CF, Lin YC, Lin CL.
    Journal: Dalton Trans; 2005 Jan 21; (2):396-401. PubMed ID: 15616732.
    Abstract:
    Free-base, nickel(II), zinc(II) and iron(III) mono(4-aniline-ethynyl)biphenylporphines (AEBPPs) were synthesized and their electro-polymerization reactions were studied. Electrochemical and UV-Visible experiments showed that AEBPPs were electro-polymerized onto Pt and indium tin oxide (ITO) surfaces without significantly changing their redox and spectral properties. This suggests that the pi-conjugations of these porphyrins were not greatly affected upon electro-polymerization. SEM images indicated the formation of porphyrin films on the electrode surfaces, while EDS spectra of the metallo-AEBPP films confirmed deposits of the corresponding metals. Upon closer inspection, the AFM images revealed nano-scale fine structure of these porphyrin films. Both SEM and AFM images of the porphyrin films showed similar trends of porphyrin accumulation.
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