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  • Title: Chemoselective construction of substituted conjugated dienes using an olefin cross-metathesis protocol.
    Author: Funk TW, Efskind J, Grubbs RH.
    Journal: Org Lett; 2005 Jan 20; 7(2):187-90. PubMed ID: 15646954.
    Abstract:
    [Reaction: see text] Various substituted conjugated dienes have been made by olefin cross-metathesis. Using either electronic or steric "protection," one of the olefins of the conjugated diene was deactivated relative to the other for cross-metathesis. The reactions proceed with very high chemoselectivity and, when steric deactivation is used, very high diastereoselectivity.
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