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  • Title: Application of the Dötz reaction to construction of a major portion of the ansa macrocycle (-)-kendomycin.
    Author: White JD, Smits H.
    Journal: Org Lett; 2005 Jan 20; 7(2):235-8. PubMed ID: 15646966.
    Abstract:
    [Reaction: see text] A Dötz reaction employing a terminal alkyne and a Fischer-type alkenylchromium carbenoid led to a pentasubstituted benzene from which a major portion of the Streptomyces metabolite (-)-kendomycin was synthesized.
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