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  • Title: Decarboxylative Claisen rearrangement reactions of allylic tosylmalonate esters.
    Author: Craig D, Grellepois F.
    Journal: Org Lett; 2005 Feb 03; 7(3):463-5. PubMed ID: 15673265.
    Abstract:
    [reaction: see text] Two different combinations of silylating agent and base are used for one-pot [3,3]-sigmatropic rearrangement-decarboxylation reactions of tosylmalonic mono(allylic) esters under mild conditions, providing the products of formal regiospecific allylation of methyl tosylacetate at the more substituted allylic terminus.
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