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  • Title: Electric-field-induced transition between the polarization-modulated and ferroelectric smectic- C(S) P(F)* liquid crystalline states studied using microbeam x-ray diffraction.
    Author: Nakata M, Link DR, Takanishi Y, Takahasi Y, Thisayukta J, Niwano H, Coleman DA, Watanabe J, Iida A, Clark NA, Takezoe H.
    Journal: Phys Rev E Stat Nonlin Soft Matter Phys; 2005 Jan; 71(1 Pt 1):011705. PubMed ID: 15697621.
    Abstract:
    We report x-ray microbeam studies of a bent-core liquid crystalline material with chiral citronellyl tails. This material has an equilibrium polarization-modulated smectic- CP (PM-SmCP) state exhibiting the B7 texture upon slow cooing from the isotropic while a metastable chiral synclinic ferroelectric Sm-CP state (Sm- C(S) P(*)(F) ) is obtained on quenching from the isotropic. The polarization modulated phase PM-Sm C(S) P(*)(F) shows typical x-ray patterns having multiple satellite peaks around the first-order layer reflection, indicating undulated layers, while the metastable Sm- C(S) P(*)(F) state exhibits a single layering peak indicating flat layers. The Sm- C(S) P(*)(F) state is also induced by the application of an electric field larger than the threshold field ( E(th) ) and thermally returns to the polarization modulated PM-Sm C(S) P(*)(F) structure.
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