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  • Title: Enantioselective radical addition/trapping reactions with alpha,beta-disubstituted unsaturated imides. Synthesis of anti-propionate aldols.
    Author: Sibi MP, Petrovic G, Zimmerman J.
    Journal: J Am Chem Soc; 2005 Mar 02; 127(8):2390-1. PubMed ID: 15724983.
    Abstract:
    This manuscript describes a highly diastereo- and enantioselective intermolecular radical addition/hydrogen atom transfer to alpha,beta-disubstituted enoates. Additionally, we show that anti-propionate aldol-like products can be easily prepared from alpha-methyl-beta-acyloxyenoates in good yields and high diastereo- and enantioselectivities.
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