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  • Title: PS-COD and PS-9-BBN: polymer-supported reagents for solution-phase parallel synthesis.
    Author: Revell JD, Dörner B, White PD, Ganesan A.
    Journal: Org Lett; 2005 Mar 03; 7(5):831-3. PubMed ID: 15727452.
    Abstract:
    1,5-Cyclooctadiene was deprotonated under LICKOR conditions and reacted with Merrifield resin to afford an immobilized cyclooctadiene in high yield. This polymer is effective as a halogen scavenger, while hydroboration leads to a supported 9-BBN analogue. The latter exhibits similar regioselectivity to 9-BBN in olefin hydroboration. [reaction: see text]
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