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  • Title: Extending Pummerer reaction chemistry. Synthesis of (+/-)-dibromophakellstatin by oxidative cyclization of an imidazole derivative.
    Author: Feldman KS, Skoumbourdis AP.
    Journal: Org Lett; 2005 Mar 03; 7(5):929-31. PubMed ID: 15727477.
    Abstract:
    The diastereoselective oxidative cyclization of a dihydrooroidin derivative is reported. The thioimidate product formed by application of a new variant of the Pummerer reaction serves as a precursor to dibromophakellstatin. [reaction: see text]
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