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  • Title: Fluoroaryl-substituted aminoalane dimers: syntheses and structures.
    Author: Shukla P, Cowley AH, Jones JN, Gordon JC, Scott BL.
    Journal: Dalton Trans; 2005 Mar 21; (6):1019-22. PubMed ID: 15739002.
    Abstract:
    Six dimeric aminoalanes of formula [Me(2)Al-mu-N(H)Ar(F)](2)(Ar(F)= 4-C(6)H(4)F (1), 2-C(6)H(4)F (2), 3,5-C(6)H(3)F(2)(3), 2,3,4,5-C(6)HF(4)(4), 2,3,5,6-C(6)HF(4)(5) and C(6)F(5)(6)) have been prepared by treatment of the appropriate fluoroaniline with AlMe(3) in toluene solution at 25 degrees C. The structures of 1-6 were determined by X-ray crystallography.
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