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Title: Cluster formation in two-Yukawa fluids. Author: Liu Y, Chen WR, Chen SH. Journal: J Chem Phys; 2005 Jan 22; 122(4):44507. PubMed ID: 15740267. Abstract: We present a different and efficient method for implementing the analytical solution of Ornstein-Zernike equation for two-Yukawa fluids in the mean spherical approximation. We investigate, in particular, the conditions for the formation of an extra low-Q peak in the structure factor, which we interpret as due to cluster formation in the two-Yukawa fluid when the interparticle potential is composed of a short-range attraction and a long-range repulsion. We then apply this model to interpret the small angle neutron scattering data for protein solutions at moderate concentrations and find out that the presence of a peak centered at Q=0 (zero-Q peak) besides the regular interaction peak due to charged proteins implies an existence of long-range attractive interactions besides the charge repulsion.[Abstract] [Full Text] [Related] [New Search]