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  • Title: Synthetic approaches and total synthesis of natural zoapatanol.
    Author: Taillier C, Gille B, Bellosta V, Cossy J.
    Journal: J Org Chem; 2005 Mar 18; 70(6):2097-108. PubMed ID: 15760193.
    Abstract:
    [structure: see text] The total synthesis of (+)-zoapatanol utilizing an intramolecular Horner-Wadsworth-Emmons olefination and an enantioselective Sharpless dihydroxylation as the key steps has been achieved. An advanced oxepene intermediate has been obtained by applying a ring-closing metathesis to an unsaturated enol ether.
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