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  • Title: Pd(OH)2/C-mediated selective oxidation of silyl enol ethers by tert-butylhydroperoxide, a useful method for the conversion of ketones to alpha,beta-enones or beta-silyloxy-alpha,beta-enones.
    Author: Yu JQ, Wu HC, Corey EJ.
    Journal: Org Lett; 2005 Mar 31; 7(7):1415-7. PubMed ID: 15787520.
    Abstract:
    [reaction: see text] Pd(OH)2-catalyzed oxidation of silyl enol ethers by t-BuOOH gives either beta-silyloxy-alpha,beta-enones or alpha,beta-enones in good yields depending on the base used.
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