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  • Title: Efficient Stille cross-coupling reaction catalyzed by the Pd(OAc)2/Dabco catalytic system.
    Author: Li JH, Liang Y, Wang DP, Liu WJ, Xie YX, Yin DL.
    Journal: J Org Chem; 2005 Apr 01; 70(7):2832-4. PubMed ID: 15787581.
    Abstract:
    [reaction: see text] An efficient Pd(OAc)2/Dabco-catalyzed Stille cross-coupling reaction procedure has been developed. In the presence of Pd(OAc)2 and Dabco (triethylenediamine), various aryl halides including aryl iodides, aryl bromides, and activated aryl chlorides were coupled efficiently with organotin compounds to afford the corresponding biaryls, alkene, and alkynes in good to excellent yields. Furthermore, high TONs [turnover numbers, up to 980,000 TONs for the coupling reaction of 1-bromo-4-nitrobenzene and furan-2-yltributyltin] for the Stille cross-coupling reaction were observed.
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