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Title: [Spectrophotometric determination of iron using eriochrome cyanine R as extractant with phase-separation]. Author: Zhang Z, Xie Y, Shi Y. Journal: Guang Pu Xue Yu Guang Pu Fen Xi; 1999 Apr; 19(2):241-3. PubMed ID: 15819022. Abstract: Spectrophotometric determination of iron by using eriochrome cyanine R as extractant and color-developing agent in organic solvents was studied. The complex was extracted by PEG phase from the water solutions of pH4.5-6.5 (NaAc-HAc). The maximum absorption of the complex is at 560 nm and the molar absorptivity is 5.36 x 10(4) L x mol(-1) x cm(-1). Beers law was obeyed in the range of 0-40 microg Fe. Iron and eriochrome cyanine R formed a stable complex with a molar ratio of 1:2. The proposed method has been applied to the determination of copper in aluminium alloys with satisfactory results.[Abstract] [Full Text] [Related] [New Search]