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  • Title: [Studies on the infrared spectra of mico2-OR or micro2-SR-bridged double-cubane-like clusters containing MoFe3S4 cores].
    Author: He L, Chen B, Cai S, Lin S, Chen C, Zhang L.
    Journal: Guang Pu Xue Yu Guang Pu Fen Xi; 1999 Oct; 19(5):666-9. PubMed ID: 15822261.
    Abstract:
    The IR spectra of micro2-OR or micro2-SR- bridged double-cubane-like clusters containing MoFe3S4 cores (Et4N)3 [Mo2Fe6S8Cl6 (OMe)3] (1), (Et4N) [Mo2Fe6S8 (SPh)6 (OMe)3 (2), (Bu4N)3 Mo2Fe6S (SPh)6 (OMe)3] (3), (Et4N)3 [Mo2Fe6S8 (SBu(t))6(OMe)3](4), (Et4N)3[Mo2Fe6S8 (SPh)9](5) have been investigated. Their characteristic frequencies (v)Mo-micro2O(R), (v)Mo-micro2S(R), (v)Mo-S, (v)Fe-S*, (v)Fe-SR, (v)Fe-Cl were assigned by comparing their vibrational frequencies with their structural parameters and by comparing the IR spectra of them with that of the linear clusters. The electrophilic induced effects in different way and the relationship between deltav (i.e. (v)Mo-S* (v)Fe-S*) and Fe --> Mo charge transfer have been discussed. Finaly, the sameness and difference between the double-cubane-like and linear Mo-Fe-S clusters were demonstrated.
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