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  • Title: Partitioning of small amphiphiles at surfactant bilayer/water interfaces: an avoided level crossing muon spin resonance study.
    Author: Scheuermann R, Tucker IM, Dilger H, Staples EJ, Ford G, Fraser SB, Beck B, Roduner E.
    Journal: Langmuir; 2004 Mar 30; 20(7):2652-9. PubMed ID: 15835133.
    Abstract:
    The temperature-dependent variation of local environment and reorientation dynamics of the small amphiphile 2-phenylethanol in lamellar phase dispersions of the dichain cationic surfactants, 2,3-diheptadecyl ester ethoxypropyl-1,1,1-trimethylammonium chloride (DHTAC) and dioctadecyldimethylammonium chloride (DODMAC), and the nonionic surfactant, tetra(ethylene glycol) n-dodecyl ether (C12E4), have been determined using avoided level crossing muon spin resonance spectroscopy (ALC-muSR). For cosurfactant radicals the hydrophobic or hydrophilic character of the surrounding media can be determined from their magnetic resonance signatures. Comparison of the three different bilayer-forming surfactant systems shows that the ALC-muSR technique is able to distinguish both major and subtle differences in the partitioning of the cosurfactant radicals between the different systems.
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