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  • Title: Efficient batch and continuous flow Suzuki cross-coupling reactions under mild conditions, catalysed by polyurea-encapsulated palladium (II) acetate and tetra-n-butylammonium salts.
    Author: Lee CK, Holmes AB, Ley SV, McConvey IF, Al-Duri B, Leeke GA, Santos RC, Seville JP.
    Journal: Chem Commun (Camb); 2005 Apr 28; (16):2175-7. PubMed ID: 15846438.
    Abstract:
    Suzuki cross-coupling reactions are effected in both conventional organic solvents, under continuous flow conditions at 70 degree C, and in batch mode in supercritical carbon dioxide (scCO2), at temperatures as low as 40 degrees C in the presence of palladium(II) acetate microencapsulated in polyurea [PdEnCat] and tetra-n-butylammonium salts.
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