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  • Title: Enantioselective allylation of aldehydes catalyzed by chiral indium(III) complexes immobilized in ionic liquids.
    Author: Lu J, Ji SJ, Loh TP.
    Journal: Chem Commun (Camb); 2005 May 14; (18):2345-7. PubMed ID: 15877123.
    Abstract:
    In the presence of chiral catalytic complexes prepared from In(OTf)3 and chiral PYBOX ligands, allytributylstannane reacted with aldehydes in ionic liquids to afford the corresponding homoallylic alcohols in high enantioselectivities (86-94% ee) and good yields (68-89%); the chiral catalysts immobilized in ionic liquids could be reused with comparable enantioselectivities and yields.
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