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  • Title: Particle distribution in a microporous material: experiments with zeolite A.
    Author: Meyer M, Leiggener C, Calzaferri G.
    Journal: Chemphyschem; 2005 Jun 13; 6(6):1071-80. PubMed ID: 15883991.
    Abstract:
    The theory on particle distribution and exchange equilibria in a microporous material is applied to experimental ion-exchange data involving zeolite Na-A and zeolite K-A, with silver ions as the exchanging species. The presented method enables direct evaluation of the measured data and consideration of nonequivalent particle sites. The isotherms of the K+ versus Ag+ exchange in zeolite K-A rise much more steeply, at low exchange degrees, than those of the Na+ versus Ag+ exchange in zeolite Na-A. This result implies a different course of the ion-exchange reactions. Spectroscopic measurements on dehydrated, partly silver-exchanged zeolites Na-A and K-A do indeed show that in zeolite Na-A, the Na+ ions occupying four-ring positions are exchanged faster for Ag+ than the Na+ ions occupying eight- and six-ring positions, while in zeolite K-A the exchange does not start with the four-ring ion but with six-ring ions, followed by the four-ring ion. These findings are consistent with the results obtained from evaluation of the ion-exchange data. The resulting thermodynamic quantities significantly differ from published reference values, which we suggest should be revised.
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