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  • Title: The study of bimolecular reactions under non-pseudo-first order conditions.
    Author: Malatesta F.
    Journal: Biophys Chem; 2005 Aug 01; 116(3):251-6. PubMed ID: 15896898.
    Abstract:
    In this work a new equation which describes the time evolution of bimolecular reactions is derived and tested by experiment. The equation is general and the results show that second-order reactions of any simple type may be accurately described by a quotient of exponential functions. The model and reagent concentration dependent observed rate constants show a complex non-linear behaviour when experimental conditions deviate from pseudo-first order nevertheless reducing to the well-known linear dependence when pseudo-first order conditions are met.
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