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  • Title: Synthesis of allenamides by copper-catalyzed coupling of allenyl halides with amides, carbamates, and ureas.
    Author: Trost BM, Stiles DT.
    Journal: Org Lett; 2005 May 26; 7(11):2117-20. PubMed ID: 15901148.
    Abstract:
    [reaction: see text]. A variety of N-substituted allenes have been synthesized by the copper-catalyzed coupling reaction between allenyl halides and amides, carbamates, and ureas. The reactions proceed in good to excellent yield using 7 mol % copper thiophenecarboxylate and 15 mol % of a diamine catalyst.
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