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  • Title: First osmium-catalysed ketamination of alkenes.
    Author: Villar A, Hövelmann CH, Nieger M, Muñiz K.
    Journal: Chem Commun (Camb); 2005 Jul 14; (26):3304-6. PubMed ID: 15983655.
    Abstract:
    Conditions for a first oxidative conversion of alkenes into 2-amino ketones are described, which yield racemic products within a direct oxidation pathway and 2-amino ketones with up to 99% enantiomeric excess from the corresponding enantiopure amino alcohols.
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