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  • Title: Synthesis, characterisation and theoretical studies of amidinato-indium(I) and thallium(I) complexes: isomers of neutral group 13 metal(I) carbene analogues.
    Author: Jones C, Junk PC, Platts JA, Rathmann D, Stasch A.
    Journal: Dalton Trans; 2005 Aug 07; (15):2497-9. PubMed ID: 16025168.
    Abstract:
    The synthesis and characterisation of the monomeric amidinato-indium(I) and thallium(I) complexes, [M(Piso)].PisoH, M = In or Tl, Piso- = [ArNC(Bu(t))NAr]-, Ar = C6H3Pr(i)2-2,6, are reported. These complexes, in which the metal centre is chelated by the amidinate ligand in an N,eta3-arene-fashion, can be considered as isomers of four-membered group 13 metal(I) carbene analogues. Theoretical studies have compared the relative energies of both isomeric forms of a model complex, [In{PhNC(H)NPh}].
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