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  • Title: Stereoselective syntheses of rolliniastatin 1, rollimembrin, and membranacin.
    Author: Keum G, Hwang CH, Kang SB, Kim Y, Lee E.
    Journal: J Am Chem Soc; 2005 Jul 27; 127(29):10396-9. PubMed ID: 16028952.
    Abstract:
    A radical cyclization of beta-alkoxyvinyl sulfoxides-Pummerer rearrangement-allylation protocol was successfully applied to the synthesis of the threo/cis/threo/cis/erythro bis-oxolane moiety in rolliniastatin 1 (1), rollimembrin (2), and membranacin (3).
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