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  • Title: Ru(IV)-catalyzed isomerization of allylamines in water: a highly efficient procedure for the deprotection of N-allylic amines.
    Author: Cadierno V, García-Garrido SE, Gimeno J, Nebra N.
    Journal: Chem Commun (Camb); 2005 Aug 28; (32):4086-8. PubMed ID: 16091808.
    Abstract:
    A general and efficient method for the deprotection of N-allylic substrates in aqueous media, using catalytic amounts of the bis(allyl)-ruthenium(IV) complexes [Ru(eta3:eta2:eta3-C12H18)Cl2] and [{Ru(eta3:eta3-C10H16)(micro-Cl)Cl}2], has been developed.
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