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  • Title: Total synthesis of (+)-epiquinamide.
    Author: Wijdeven MA, Botman PN, Wijtmans R, Schoemaker HE, Rutjes FP, Blaauw RH.
    Journal: Org Lett; 2005 Sep 01; 7(18):4005-7. PubMed ID: 16119953.
    Abstract:
    The stereoselective total synthesis of the novel quinolizidine alkaloid (+)-epiquinamide is presented, starting from the amino acid l-allysine ethylene acetal. Key steps in the synthesis involved a highly diastereoselective N-acyliminium ion allylation and a ring-closing metathesis reaction to provide the bicyclic skeleton. [reaction: see text]
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