These tools will no longer be maintained as of December 31, 2024. Archived website can be found here. PubMed4Hh GitHub repository can be found here. Contact NLM Customer Service if you have questions.


PUBMED FOR HANDHELDS

Search MEDLINE/PubMed


  • Title: Facile approach to 2-acetamido-2-deoxy-beta-D-glucopyranosides via a furanosyl oxazoline.
    Author: Cai Y, Ling CC, Bundle DR.
    Journal: Org Lett; 2005 Sep 01; 7(18):4021-4. PubMed ID: 16119957.
    Abstract:
    A concise and convenient route that may be easily scaled is reported for the preparation of unprotected beta-glucopyranosides of N-acetyl-D-glucosamine. Reaction of a wide variety of alcohols with a reactive, readily prepared furanosyl oxazoline under acidic conditions affords the corresponding beta-D-glucopyranosides in good to high yields. Primary alcohols gave only beta-D-glucopyranosides. A mechanism is proposed for this transformation. [reaction: see text]
    [Abstract] [Full Text] [Related] [New Search]