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  • Title: Enantioselective reduction of imines catalyzed by a rhenium(V)-oxo complex.
    Author: Nolin KA, Ahn RW, Toste FD.
    Journal: J Am Chem Soc; 2005 Sep 14; 127(36):12462-3. PubMed ID: 16144373.
    Abstract:
    An air- and moisture-tolerant enantioselective hydrosilylation of N-phosphinyl imines employing a chiral Re(V)-oxo complex as a catalyst is described. The chiral catalyst is a cyanobis(oxazoline) (CNbox)-ligated rhenium-oxo complex of the general formula (CNbox)Re(O)Cl2(OPPh3). Using this catalyst, a wide range of aromatic imines (including cyclic, acyclic, and heteroaromatic), alpha-iminoesters, and alpha,beta-unsaturated imines are reduced with good to excellent enantioselectivities.
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