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  • Title: Toward the synthesis of spirastrellolide a: construction of a tetracyclic C26-C40 subunit containing the DEF-bis-spiroacetal.
    Author: Paterson I, Anderson EA, Dalby SM, Loiseleur O.
    Journal: Org Lett; 2005 Sep 15; 7(19):4121-4. PubMed ID: 16146367.
    Abstract:
    [reaction: see text] A stereo-controlled synthesis of the fully elaborated C26-C40 tricyclic [5,6,6]-bis-spiroacetal of spirastrellolide A containing the C28 chlorine substituent is reported, exploiting asymmetric Sharpless dihydroxylation and boron-mediated allylation methodology.
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