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  • Title: Enantioselective RH-catalyzed hydrogenation of enol acetates and enol carbamates with monodentate phosphoramidites.
    Author: Panella L, Feringa BL, de Vries JG, Minnaard AJ.
    Journal: Org Lett; 2005 Sep 15; 7(19):4177-80. PubMed ID: 16146381.
    Abstract:
    [reaction: see text] Monodentate phosphoramidites, in particular PipPhos and its octahydro analogue, are excellent ligands for the rhodium-catalyzed asymmetric hydrogenation of aromatic enol acetates, enol carbamates, and 2-dienol carbamates up to 98% ee. These latter substrates were hydrogenated selectively to the carbamates of the allyl alcohol.
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