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  • Title: Chemistry of tetrathiomolybdate: aziridine ring opening reactions and facile synthesis of interesting sulfur heterocycles.
    Author: Sureshkumar D, Koutha SM, Chandrasekaran S.
    Journal: J Am Chem Soc; 2005 Sep 21; 127(37):12760-1. PubMed ID: 16159244.
    Abstract:
    Benzyltriethylammonium tetrathiomolybdate, [BnEt3N]2MoS4, has been used successfully to effect ring opening of aziridines in a regiospecific and stereospecific manner under mild reaction conditions without the use of Lewis acid catalyst. Utility of this reagent in tandem and multistep processes in a one-pot operation for the synthesis of various novel sulfur heterocycles in very good yield is also reported.
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