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  • Title: Efficient and stereodivergent synthesis of deoxyimino sugars.
    Author: Hong BC, Chen ZY, Nagarajan A, Kottani R, Chavan V, Chen WH, Jiang YF, Zhang SC, Liao JH, Sarshar S.
    Journal: Carbohydr Res; 2005 Nov 21; 340(16):2457-68. PubMed ID: 16169539.
    Abstract:
    Both cis- and trans-2-substituted-1,2,3,6-tetrahydro-pyridin-3-ols have been prepared via an aldol condensation-ring-closing metathesis sequence. A stereodivergent synthesis of optionally functionalized deoxyimino sugars was achieved via asymmetric dihydroxylation or epoxidation/nucleophilic substitution of these tetrahydropyridines.
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