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  • Title: Chemical optimization of artificial metalloenzymes based on the biotin-avidin technology: (S)-selective and solvent-tolerant hydrogenation catalysts via the introduction of chiral amino acid spacers.
    Author: Skander M, Malan C, Ivanova A, Ward TR.
    Journal: Chem Commun (Camb); 2005 Oct 14; (38):4815-7. PubMed ID: 16193124.
    Abstract:
    Incorporation of biotinylated-[rhodium(diphosphine)]+ complexes, with enantiopure amino acid spacers, in streptavidin affords solvent-tolerant and selective artificial metalloenzymes: up to 91% ee (S) in the hydrogenation of N-protected dehydroamino acids.
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