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  • Title: Palladium-catalyzed allylation of acidic and less nucleophilic anilines using allylic alcohols directly.
    Author: Hsu YC, Gan KH, Yang SC.
    Journal: Chem Pharm Bull (Tokyo); 2005 Oct; 53(10):1266-9. PubMed ID: 16204982.
    Abstract:
    The direct activation of C-O bonds in allylic alcohols by palladium complexes has been accelerated by carrying out the reactions in the presence of titanium(IV) isoproxide and 4 A molecular sieves. The acidic and less nucleophilic anilines such as diphenylamine, phenothiazine, 4-cyanoaniline, and nitroanilines are efficiently allylated under palladium catalysis using allylic alcohols as allylating reagents.
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