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  • Title: Organocatalytic asymmetric Michael addition of 2,4-pentandione to nitroolefins.
    Author: Wang J, Li H, Duan W, Zu L, Wang W.
    Journal: Org Lett; 2005 Oct 13; 7(21):4713-6. PubMed ID: 16209517.
    Abstract:
    [reaction: see text] A novel binaphthyl-derived amine thiourea organocatalyst has been developed and demonstrated to efficiently catalyze Michael addition reactions (using as low as 1 mol % loading) of diketones to nitroalkenes with remarkably high enantioselectivities.
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