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  • Title: Positional control of encapsulated atoms inside a fullerene cage by exohedral addition.
    Author: Yamada M, Nakahodo T, Wakahara T, Tsuchiya T, Maeda Y, Akasaka T, Kako M, Yoza K, Horn E, Mizorogi N, Kobayashi K, Nagase S.
    Journal: J Am Chem Soc; 2005 Oct 26; 127(42):14570-1. PubMed ID: 16231899.
    Abstract:
    The exohedrally functionalized derivative of endohedral metallofullerene, Ce2@C80(Mes2SiCH2SiMes2), was successfully synthesized and fully characterized. X-ray crystallographic and NMR spectroscopic analyses reveal that the free random motion of two metal atoms in Ce2@C80 is controlled inside the cage by exohedral chemical functionalization.
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