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  • Title: Highly stereoselective reductions of alpha-alkyl-1,3-diketones and alpha-alkyl-beta-keto esters catalyzed by isolated NADPH-dependent ketoreductases.
    Author: Kalaitzakis D, Rozzell JD, Kambourakis S, Smonou I.
    Journal: Org Lett; 2005 Oct 27; 7(22):4799-801. PubMed ID: 16235892.
    Abstract:
    [reaction: see text] The biocatalytic reduction of alpha-alkyl-1,3-diketones and alpha-alkyl-beta-keto esters employing 1 of 20 different isolated NADPH-dependent ketoreductases proved to be a highly efficient method for the preparation of optically pure keto alcohols or hydroxy esters.
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