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  • Title: Palladium-catalyzed conversion of benzylic and allylic halides into alpha-aryl and beta,gamma-unsaturated tertiary amides by the use of a carbamoylsilane.
    Author: Cunico RF, Pandey RK.
    Journal: J Org Chem; 2005 Oct 28; 70(22):9048-50. PubMed ID: 16238350.
    Abstract:
    [reaction: see text] Treatment of allylic and benzylic halides with N,N-dimethylcarbamoyl(trimethyl)silane in the presence of tetrakis(triphenylphosphine)palladium(0) affords tertiary amides, which arise from the replacement of the halogen by the N,N-dimethylcarbamoyl group.
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